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Glycerol is a coproduct of biodiesel, which is derived from rapeseed or sunflower and can be blended with diesel fuel. This coproduct could be commercially processed as an intermediate chemical for the synthesis of speciality products such as lubricants. Glycerol converted into glycerol carbonate is a reagent of choice that can be made to react, for example, with rapeseed methyl esters themselves. It would be useful to validate these syntheses and to test the properties of the products obtained in order to find market outlets for them. The aim of this project is to study the simultaneous, value-added processing of rapeseed methyl esters and glycerol. The first stage will study the acylation of glycerol carbonate by esterification. The second stage will study the acylation of glycerol carbonate by transesterification. The third stage will examine the acylation of glycerol carbonate in the presence of acid chlorides. The fourth stage will be devoted to evaluation and performance testing of the products for uses as lubricants, plastifiers and emulsion agents. |
Potential outlets for these products are the following: lubricant applications, for instance machining of metallic parts; plastifier additives used in plastics to facilitate working with polymers; emulsifier additives used in cosmetics and food processing to stabilise emulsions. |
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| Abstract The invention concerns a method for preparing glycerol carbonate. This method consists of making urea and glycerol react at a temperature substantially between 90.degree. C. and 220.degree. C. in the presence of a catalyst bearing Lewis acid sites, in particular metallic or organometallic salts or supported metallic compounds. The invention enables glycerol carbonate to be obtained, by a catalytic carbamoylation/carbonation reaction, in a highly pure |
| Abstract | Drawing | Description | ClaimsAbstract The invention concerns a method for preparing glycerol carbonate. This method consists of making urea and glycerol react at a temperature substantially between 90.degree. C. and 220.degree. C. in the presence of a catalyst bearing Lewis acid sites, in particular metallic or organometallic salts or supported metallic compounds. The invention enables glycerol carbonate to be obtained, by a catalytic carbamoylation/carbonation reaction, in a highly pure |
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Latest page update: made by pannirbr
, Aug 16 2008, 7:16 AM EDT
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bioplastics
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